HF stretching-bending combination bands for small complexes in solid argon

被引：10

作者：

Andrews, L ^{[1
]}

Souter, PF ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22901 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1999年 / 111卷 / 13期

关键词：

D O I：

10.1063/1.479895

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared spectra of HF (with DF substitution) in solid argon contain weak HF stretching-bending combination bands for N-2-HF, (HF)(2), and (HF)(3) that are higher than the sum of fundamentals. This is in accord with stronger hydrogen bonds upon vibrational excitation of the H-F stretching mode, as observed in the gas phase. Overtone bands were also observed for DF and (DF)(2) in solid argon. (C) 1999 American Institute of Physics. [S0021-9606(99)01537-8].

引用

页码：5995 / 5998

页数：4

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