Acylation of aromatic compounds using moisture insensitive InCl3 impregnated mesoporous Si-MCM-41 catalyst

被引:45
作者
Choudhary, VR [1 ]
Jana, SK [1 ]
Patil, NS [1 ]
机构
[1] Natl Chem Lab, Div Chem Engn, Pune 411008, Maharashtra, India
关键词
acylation of aromatic compounds; InCl3 impregnated mesoporous Si-MCM-41 catalyst;
D O I
10.1016/S0040-4039(01)02335-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Acylation of aromatic compounds (benzene, toluene, p-xylene, mesitylene, anisole, naphthalene, methylnaphthalene and methoxynaphthalene) by an acyl chloride (benzoyl chloride. phenylacety chloride, propionyl chloride or butyryl chloride) in high yield, in a short reaction period (3 h), even in the presence of moisture in the aromatic substrate or solvent (dichloroethane), can be accomplished at low temperature (80+/-1degreesC) using an InCl3 impregnated Si-MCM-41 catalyst in low catalyst concentration. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1105 / 1107
页数:3
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