Supramolecular shuttle and protective agent:: a multiple role of methylated cyclodextrins in the chemoselective hydrogenation of benzene derivatives with ruthenium nanoparticles

被引:83
作者
Nowicki, A
Zhang, Y
Léger, B
Rolland, JP
Bricout, H
Monflier, E
Roucoux, A
机构
[1] Ecole Natl Super Chim Rennes, Inst Chim Rennes, CNRS, UMR Synth & Activat Biomol 6052, F-35700 Rennes, France
[2] Univ Rennes 1, CNRS, UMR Interact Cellulaires & Mol 6026, Rennes, France
[3] Univ Artois, Fac Jean Perrin, FRE 2485, CNRS,Lab Physicochim Interfaces & Applicat, F-62307 Lens, France
关键词
D O I
10.1039/b512838b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Efficient chemoselectivities have been obtained in the hydrogenation of benzene derivatives under biphasic liquid-liquid conditions using Ru(0) nanoparticles stabilized and controlled by the relevant choice of cavity and methylation degree of cyclodextrins.
引用
收藏
页码:296 / 298
页数:3
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