Niger Delta oil geochemistry: Insight from light hydrocarbons

被引:26
作者
Akinlua, A [1 ]
Ajayi, TR
Adeleke, BB
机构
[1] Obafemi Awolowo Univ, Dept Chem, Ife, Nigeria
[2] Obafemi Awolowo Univ, Dept Geol, Ife, Nigeria
[3] Univ Ibadan, Dept Chem, Ibadan, Nigeria
关键词
light hydrocarbons; niger delta; biodegradation; evaporative fractionation;
D O I
10.1016/j.petrol.2005.12.003
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A suite of oil samples from an onshore-swamp field in the northwestern Niger Delta was analyzed using whole oil gas chromatography. The oil samples were analyzed to correlate the oils and to evaluate post generative alterations using light hydrocarbons. Light hydrocarbon based parameters were compared with higher molecular weight hydrocarbon correlation based parameters. Two distinct oil groups were identified based on light hydrocarbon parameters, which agreed with the correlation based on higher molecular weight hydrocarbon parameters. The discrimination of the two groups is a reflection of post generative alteration-biodegradation. The study showed that light hydrocarbon distribution has strong influence on evaporative fractionation of the oils. It also revealed that the process that initiates biodegradation has significant influence on carbocyclic ring closure. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:308 / 314
页数:7
相关论文
共 18 条
[1]  
Ahsan A., 2000, PETROLEUM GEOCHEMIST, P57
[2]  
Akinlua A, 2000, PETROLEUM GEOCHEMIST, P81
[3]   OIL-GENERATING COALS OF THE SAN-JUAN BASIN, NEW-MEXICO AND COLORADO, USA [J].
CLAYTON, JL ;
RICE, DD ;
MICHAEL, GE .
ORGANIC GEOCHEMISTRY, 1991, 17 (06) :735-742
[4]   C-24-C-27 DEGRADED TRITERPANES IN NIGERIAN PETROLEUM - NOVEL MOLECULAR MARKERS OF SOURCE-INPUT OR ORGANIC MATURATION [J].
EKWEOZOR, CM ;
OKOGUN, JI ;
EKONG, DEU ;
MAXWELL, JR .
JOURNAL OF GEOCHEMICAL EXPLORATION, 1981, 15 (1-3) :653-662
[5]   Geochemical correlation of crude oils in the NW Niger Delta, Nigeria [J].
Eneogwe, C ;
Ekundayo, O .
JOURNAL OF PETROLEUM GEOLOGY, 2003, 26 (01) :95-103
[6]   Macromolecular biophysics of the plant cell wall: Concepts and methodology [J].
Jarvis, MC ;
McCann, MC .
PLANT PHYSIOLOGY AND BIOCHEMISTRY, 2000, 38 (1-2) :1-13
[7]   THE ORIGIN OF LIGHT-HYDROCARBONS IN PETROLEUM - A KINETIC TEST OF THE STEADY-STATE CATALYTIC HYPOTHESIS [J].
MANGO, FD .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1990, 54 (05) :1315-1323
[8]   The light hydrocarbons in petroleum: a critical review [J].
Mango, FD .
ORGANIC GEOCHEMISTRY, 1997, 26 (7-8) :417-440
[9]   THE ORIGIN OF LIGHT CYCLOALKANES IN PETROLEUM [J].
MANGO, FD .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1990, 54 (01) :23-27
[10]   THE ORIGIN OF LIGHT-HYDROCARBONS IN PETROLEUM - RING PREFERENCE IN THE CLOSURE OF CARBOCYCLIC RINGS [J].
MANGO, FD .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1994, 58 (02) :895-901