Oxidation of organic sulfides with clay-supported iodosylbenzene as oxygen donor

被引：29

作者：

Kannan, P

Sevvel, R

Rajagopal, S

Pitchumani, K

Srinivasan, C

机构：

[1] MADURAI KAMARAJ UNIV,SCH CHEM,MADURAI 625021,TAMIL NADU,INDIA

[2] MADURAI KAMARAJ UNIV,DEPT MAT SCI,MADURAI 625021,TAMIL NADU,INDIA

来源：

TETRAHEDRON | 1997年 / 53卷 / 22期

关键词：

D O I：

10.1016/S0040-4020(97)00430-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkyl, aryl and diaryl sulfides afford excellent yields of sulfoxides with PhIO supported on natural (montmorillonite, KSF and bentonite clay) as well as cation-exchanged clays of K10-montmorillonite in acetonitrile suspension and also in solid state. A Ligand coupling mechanism for this facile oxidation is proposed. (C) 1997 Elsevier Science Ltd.

引用

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页码：7635 / 7640

页数：6

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