Synthesis and molecular structure of the all-trans- and the trans-cis-[UO2Br2(OAsPh3)2] isomers

被引：13

作者：

Arnáiz, FJ

Miranda, MJ

Aguado, R

Mahía, J

Maestro, MA

机构：

[1] Univ Burgos, Lab Quim Inorgan, E-09001 Burgos, Spain

[2] Univ A Coruna, Serv Xerais Apoio Invest, E-15071 La Coruna, Spain

来源：

POLYHEDRON | 2001年 / 20卷 / 28期

关键词：

actinides; isomers; dioxouranium(VI) bromides; uranyl bromides; triphenylarsine oxide;

D O I：

10.1016/S0277-5387(01)00957-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The all-trans and the trans-cis, isomers of [UO2Br2(OAsPh3)(2)] have been prepared by reacting UO2Br2.xH(2)O with OAsPh3. The molecular structures for both isomers have been established by X-ray diffraction analysis. The all-trans isomer is singular as the two U-OAsPh3 bonds are very different. (C) 2001 Elsevier Science Ltd. All rights reserved.

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页码：3295 / 3299

页数：5

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