Enzyme-catalyzed ring-opening polymerization of 1,3-dioxan-2-one to poly(trimethylene carbonate)

被引：121

作者：

Matsumura, S

Tsukada, K

Toshima, K

机构：

[1] Keio Univ, Yokohama

来源：

MACROMOLECULES | 1997年 / 30卷 / 10期

关键词：

D O I：

10.1021/ma961862g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The preparation of poly(trimethylene carbonate) [P(TMC)] by the enzymatic ring-opening polymerization of the six member, 1,3-dioxan-2-one (TMC) is studied with respect to the reaction conditions and origin of the enzyme. It was found that cyclic carbonate TMC was readily polymerized in the presence of lipase at the corresponding P(TMC). No elimination of carbon dioxide by the enzymatic preparation of TMC was detected.

引用

页码：3122 / 3124

页数：3

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