Enzyme-catalyzed ring-opening polymerization of 1,3-dioxan-2-one to poly(trimethylene carbonate)

被引：120

作者：

Matsumura, S

Tsukada, K

Toshima, K

机构：

[1] Keio Univ, Yokohama

来源：

MACROMOLECULES | 1997年 / 30卷 / 10期

关键词：

D O I：

10.1021/ma961862g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The preparation of poly(trimethylene carbonate) [P(TMC)] by the enzymatic ring-opening polymerization of the six member, 1,3-dioxan-2-one (TMC) is studied with respect to the reaction conditions and origin of the enzyme. It was found that cyclic carbonate TMC was readily polymerized in the presence of lipase at the corresponding P(TMC). No elimination of carbon dioxide by the enzymatic preparation of TMC was detected.

引用

页码：3122 / 3124

页数：3

共 36 条

[1] SYNTHESIS AND CHARACTERIZATION OF POLY(1,5-DIOXEPAN-2-ONE-CO-L-LACTIC ACID) AND POLY(1,5-DIOXEPAN-2-ONE CO-D,L-LACTIC ACID) [J].

ALBERTSSON, AC ;

LOFGREN, A .

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1995, A32 (01) :41-59

[2] SYNTHESIS OF COPOLYMERS OF 1,3-DIOXAN-2-ONE AND OXEPAN-2-ONE USING COORDINATION CATALYSTS [J].

ALBERTSSON, AC ;

EKLUND, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1994, 32 (02) :265-279

[3] INFLUENCE OF MOLECULAR-STRUCTURE ON THE DEGRADATION MECHANISM OF DEGRADABLE POLYMERS - IN-VITRO DEGRADATION OF POLY(TRIMETHYLENE CARBONATE), POLY(TRIMETHYLENE CARBONATE-CO-CAPROLACTONE), AND POLY(ADIPIC ANHYDRIDE) [J].

ALBERTSSON, AC ;

EKLUND, M .

JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 57 (01) :87-103

[4] HOMOPOLYMERIZATION OF 1,3-DIOXAN-2-ONE TO HIGH-MOLECULAR-WEIGHT POLY(TRIMETHYLENE CARBONATE) [J].

ALBERTSSON, AC ;

SJOLING, M .

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1992, 29 (01) :43-54

[5]

[Anonymous], MACROMOL CHEM

[6] CATIONIC COPOLYMERIZATION OF CYCLIC CARBONATE AND EPOXIDE VIA INTERMEDIATE SPIRO ORTHOCARBONATE [J].

ARIGA, T ;

TAKATA, T ;

ENDO, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1994, 32 (07) :1393-1397

[7] ALKYL HALIDE-INITIATED CATIONIC POLYMERIZATION OF CYCLIC CARBONATE [J].

ARIGA, T ;

TAKATA, T ;

ENDO, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (02) :581-584

[8] ANALYSIS AND CHARACTERIZATION OF RESORBABLE DL-LACTIDE TRIMETHYLENE CARBONATE COPOLYESTERS [J].

BUCHHOLZ, B .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1993, 4 (04) :381-388

[9]

Carothers W.H., 1932, J. Am. Chem. Soc, V54, P761, DOI DOI 10.1021/JA01341A046

[10] Studies on polymerization and ring formation. III. Glycol esters of carbonic acid [J].

Carothers, WH ;

Van Natta, FJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1930, 52 :314-326

← 1 2 3 4 →