Preparation of PEDOT/Cu composite film by in situ redox reaction between EDOT and copper(II) chloride

被引：31

作者：

Cho, M. S. ^{[2
]}

Kim, S. Y. ^{[1
]}

Nam, J. D. ^{[3
]}

Lee, Y. ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Dept Chem Engn, Suwon 440746, South Korea

[2] Sungkyunkwan Univ, Polymer Technol Inst, Suwon 440746, South Korea

[3] Sungkyunkwan Univ, Dept Polymer Sci & Engn, Suwon 440746, South Korea

来源：

SYNTHETIC METALS | 2008年 / 158卷 / 21-24期

关键词：

Copper; PEDOT; Composites; In situ vapor polymerization;

D O I：

10.1016/j.synthmet.2008.06.003

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Poly(3,4-ethylenedioxythiophene)/copper (PEDOT/Cu) composites were prepared by an in situ redox reaction of 3,4-ethylenedioxythiophene (EDOT) and copper(II) chloride. During the reaction, EDOT was oxidatively polymerized by Cu(II) chloride, while the Cu(II) ions were reduced to produce Cu metal particles. PEDOT/Cu composite films were also successfully prepared on CuCl2-coated poly(ethylene terephthalate) (PET) films by the vapor phase polymerization of EDOT. PEDOT/Cu films were characterized using UV-vis spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) to confirm the formation of PEDOT, and the presence of metallic Cu particles. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：865 / 869

页数：5

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