Study of metal clusters intercalation into cellulose by WAXS, spectroscopic, and microscopic methods

被引：11

作者：

Kotelnikova, NE

Paakkari, T

Serimaa, R

Wegener, G

Kotelnikov, VP

Demidov, VN

Schukarev, AV

Windeisen, E

Knozinger, H

Kudryashov, VI

Serebryakov, AS

机构：

[1] UNIV HELSINKI,DEPT PHYS,FIN-00014 HELSINKI,FINLAND

[2] UNIV MUNICH,WOOD RES INST,D-80797 MUNICH,GERMANY

[3] THESA CO LTD,ST PETERSBURG 197198,RUSSIA

[4] STATE TECHNOL INST,ST PETERSBURG 198019,RUSSIA

[5] JOINT STOCK CO MECHANOBR ANALYT,ST PETERSBURG 199026,RUSSIA

[6] UNIV MUNICH,INST PHYS CHEM,D-81679 MUNICH,GERMANY

[7] VG KHLOPIN RADIUM INST,ST PETERSBURG 194021,RUSSIA

来源：

MACROMOLECULAR SYMPOSIA | 1997年 / 114卷

关键词：

D O I：

10.1002/masy.19971140120

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Cellulose substrates are increasingly used as supports and fillers in medicine, as membranes and components of organic sensors. In the present paper the WAXS as well as SEM, TEM, XRF, EDXA, ESCA, FTIR, Raman, and C-13 NMR were used to study methods of metal clusters intercalation (taking as an example silver clusters) into the cellulose matrix and changes of cellulose structure in the resulting samples in bulk after this intercalation. Clusters in matrix can be formed simultaneously with the appearance of the metal phase proper on the cellulose surface. Some paths for intercalation of regularly distributed highly dispersed metal particles are shown.

引用

页码：165 / 171

页数：7

共 4 条

[1] CRYSTALS OF CELLULOSE GROWN FROM TFA SOLUTION [J].