Novel concept for low temperature curing powder coatings based on hyperbranched polyesters

被引:85
作者
Johansson, M [1 ]
Malmstöm, E [1 ]
Jansson, A [1 ]
Hult, A [1 ]
机构
[1] Royal Inst Technol, Dept Polymer Technol, SE-10044 Stockholm, Sweden
来源
JOURNAL OF COATINGS TECHNOLOGY | 2000年 / 72卷 / 906期
关键词
D O I
10.1007/BF02698470
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The concept of using hyperbranched polymers as scaffolds for solid thermoset resin applications is described. A series of semi-crystalline methyacrylate-functional aliphatic polyesters has been synthesized and characterized for applications as solid thermoset resins, e.g., powder coating resins. The polyester resins have been crosslinked by UV irradiation producing either amorphous or semi-crystalline crosslinked films depending on the initial structure. The resins are based on hyperbranched aliphatic polyester chains have been grafted and end-capped with methacrylate moieties. The resins exhibit a rheological behavior suitable for low temperature curing powder coatings, i.e., films that can be readily formed and UV cured at temperatures below 80 degrees C.
引用
收藏
页码:49 / 54
页数:6
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