Preparation of bioactive podolactones via a new Pd-catalysed bislactonisation reaction.: Synthesis of oidiolactone C

被引：12

作者：

Barrero, AF ^{[1
]}

Del Moral, JFQ ^{[1
]}

Cuerva, JM ^{[1
]}

Cabrera, E ^{[1
]}

Jiménez-González, D ^{[1
]}

机构：

[1] Univ Granada, Fac Ciencias, Dept Quim Organ, Inst Biotecnol, E-18071 Granada, Spain

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 27期

关键词：

palladium; bislactonisation; elimination reactions; dienes; natural products; herbicides;

D O I：

10.1016/S0040-4039(00)00815-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new route towards podolactone skeleton compounds, including the recently discovered Oidiolactone C, is described, using Pd-catalysed elimination of allylic trifluoroacetates and Pd-catalysed bislactonisation as key steps. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：5203 / 5206

页数：4

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