Nonstoichiometry and transport properties of strontium-substituted lanthanum cobaltites

被引:59
作者
Sitte, W
Bucher, E
Preis, W
机构
[1] Univ Min & Met Leoben, Inst Chem Phys, A-8700 Leoben, Austria
[2] Graz Univ Technol, Inst Phys & Theoret Chem, A-8010 Graz, Austria
基金
奥地利科学基金会;
关键词
lanthanum strontium cobaltite; glycine nitrate process; oxygen nonstoichiometry; electronic conductivity; chemical diffusion coefficient; surface exchange coefficient;
D O I
10.1016/S0167-2738(02)00503-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In La1-xSrxCoO3-delta (LSC), the oxygen nonstoichiometry and transport properties change with variations in Sr content, temperature and oxygen partial pressure. The purpose of this study was to investigate and correlate these parameters. The extent of oxygen deficiency was investigated by oxygen exchange measurements over the range from 300 to 900 degreesC and 1.9 X 10(-2) greater than or equal top(O2)greater than or equal to1.0 X 10(-4) bar. The oxygen deficiency was found to increase with decreasing oxygen partial pressure and/or increasing temperature. The chemical diffusion coefficient and the surface oxygen exchange coefficient were determined simultaneously by fitting transient re-equilibration curves to the respective diffusion equation at T=725 degreesC. The electronic conductivity was studied as a function of temperature and oxygen partial pressure at 1.9 X 10(-2)less than or equal top(O2)less than or equal to1.0 X 10(-4) bar. Furthermore, these data were correlated with those of the nonstoichiometry to yield conductivity values for constant oxygen content. In the case of La0.6Sr0.4CoO3-delta (LSC04), the temperature dependence of the isostoichiometric conductivities yields activation energies of 0.02less than or equal toE(a)less than or equal to0.05 eV. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:517 / 522
页数:6
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