Electrochemical synthesis and characterization of poly [3-(ω-bromoalkyl)thiophene]s

被引：6

作者：

Ballarin, Barbara

Lanzi, Massimiliano

Paganin, Luisa

Cesari, Gaia

机构：

[1] Univ Bologna, Dipartimento Chim Fis & Inorgan, I-40136 Bologna, Italy

[2] Univ Bologna, Dipartimento Chim Ind & Mat, I-40136 Bologna, Italy

来源：

ELECTROCHIMICA ACTA | 2007年 / 52卷 / 12期

关键词：

beta-substituted polythiophene; poly[3-(omega-bromoalkyl)thiophene]s; electrodeposition; polymer films; conducting polymer;

D O I：

10.1016/j.electacta.2006.11.026

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A novel series of functionalized polythiophenes incorporating 3-(omega-bromoalkyl) pendants are synthesized by electrochemical polymerization. The effect of the solvent on the electrosynthesis is investigated. The polymeric films are characterized using cyclic voltammetry, Fr-IR, AFM and SEM microscopy. The poly [3-(6-bromohexyl)thiophene] film cast on GC or ITO electrode surface is compared with a sample obtained by a chemical method. (c) 2006 Elsevier Ltd. All rights reserved.

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收藏

页码：4087 / 4091

页数：5

相关论文

共 19 条

[1] A conformational study of 2,5′-bithiophenes substituted in position 3 by halogen atoms correlated with conducting and electrochemical properties of poly(3-halogenothiophene)s [J].

Bethmont, V ;

El Kassmi, A ;

Fache, F ;

Lemaire, M .

SYNTHETIC METALS, 1998, 93 (03) :197-201

[2] Solvent effect on the nucleation and growth mechanisms of poly(thiophene) [J].

del Valle, MA ;

Cury, P ;

Schrebler, R .

ELECTROCHIMICA ACTA, 2002, 48 (04) :397-405

[3] Monomers of 3-alkyl-substituted thiophene: synthetic routes for the functionalization with non-linear optical chromophores [J].

Della-Casa, C ;

Costa-Bizzarri, P ;

Lanzi, M ;

Paganin, L ;

Bertinelli, F ;

Pizzoferrato, R ;

Sarcinelli, F ;

Casalboni, M .

SYNTHETIC METALS, 2003, 138 (03) :409-417

[4] Phenylene-functionalized polythiophene derivatives for light-emitting diodes: their synthesis, characterization and properties [J].

Ding, AL ;

Pei, J ;

Lai, YH ;

Huang, W .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (12) :3082-3086

[5] Poly[(1-methylene-2-methylnaphthalene)-N-pyrrole]: A new fluorophore-containing electroactive conducting polymer [J].

GningueSall, D ;

Kone, A ;

Aaron, JJ ;

Aeiyach, S ;

Hedayatullah, M ;

Lacaze, PC .

SYNTHETIC METALS, 1996, 82 (02) :119-127

[6] ELECTROCHEMICALLY INDUCED STRUCTURAL-CHANGES IN CONDUCTING POLYMERS [J].

HEINZE, J ;

BILGER, R ;

MEERHOLZ, K .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1988, 92 (11) :1266-1271

[7] ELECTROCHEMISTRY OF CONDUCTING POLYMERS [J].

HEINZE, J .

SYNTHETIC METALS, 1991, 43 (1-2) :2805-2823

[8] Electron and proton conducting polymers: recent developments and prospects [J].

Inzelt, G ;

Pineri, M ;

Schultze, JW ;

Vorotyntsev, MA .

ELECTROCHIMICA ACTA, 2000, 45 (15-16) :2403-2421

[9]

Lanzi M, 2002, MACROMOL RAPID COMM, V23, P630, DOI 10.1002/1521-3927(20020701)23:10/11<630::AID-MARC630>3.0.CO

[10]

2-9