Multiarm Star Block and Multiarm Star Mixed-Block Copolymers via Azide-Alkyne Click Reaction

被引：43

作者：

Durmaz, Hakan ^{[2
]}

Dag, Aydan ^{[2
]}

Erdogan, Elif ^{[2
]}

Demirel, A. Levent ^{[1
]}

Hizal, Gurkan ^{[2
]}

Tunca, Umit ^{[2
]}

机构：

[1] Koc Univ, Dept Chem, TR-34450 Istanbul, Turkey

[2] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2010年 / 48卷 / 01期

关键词：

atomic force microscopy (AFM); azide-alkyne click reaction; dynamic light scattering (DLS); GPC; multiarm star polymer; triple detection-GPC; SELECTIVE DEGRADABLE LINKAGES; ONE-POT SYNTHESIS; DIELS-ALDER; RADICAL POLYMERIZATION; TERMINAL ALKYNES; CHEMISTRY; POLYMERS; COMBINATION; CYCLOADDITION; ATRP;

D O I：

10.1002/pola.23765

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of multiarm star block (and mixed-block) copolymers are efficiently prepared by using Cu(I) catalyzed azide-alkyne click reaction and the arm-first approach. alpha-Silyl protected alkyne polystyrene (alpha-silyl-alkyne-PS) was prepared by ATRP of styrene (St) and used as macroinitiator in a crosslinking reaction with divinyl benzene to successfully give multiarm star homopolymer with alkyne periphery. Linear azide end-functionalized poly(ethylene glycol) (PEG-N-3) and poly (tert-butyl acrylate) (PtBA-N-3) were simply clicked with the multiarm star polymer described earlier to form star block or mixed-block copolymers in N,N-dimethyl formamide at room temperature for 24 h. Obtained multiarm star block and mixed-block copolymers were identified by using H-1 NMR, GPC, triple detection-GPC, atomic force microscopy, and dynamic light scattering measurements. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 99-108, 2010

引用

页码：99 / 108

页数：10

共 34 条

[1] A3-type star polymers via click chemistry [J].