One-pot synthesis of 2,5-diethynyl-3,4-dibutylthiophene substituted multitopic bipyridine ligands: redox and photophysical properties of their ruthenium(II) complexes

被引:31
作者
De Nicola, A
Liu, Y
Schanze, KS
Ziessel, R
机构
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[2] ECPM, UMR 7008, Lab Chim Mol, F-67087 Strasbourg 02, France
关键词
D O I
10.1039/b210279j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile and original synthesis of four 2,2'-bipyridine (bipy) ligands grafted with thiophene subunits is described using phase transfer experimental conditions: related Ru(II) complexes exhibit well-defined redox and photophysical properties which were probed by cyclic voltammetry, UV-vis, steady-state emission and transient absorption spectroscopy.
引用
收藏
页码:288 / 289
页数:2
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