Dispersion of nano-sized 7-alumnina powder in non-polar solvents

被引:74
作者
Liu, JC
Jean, JH [1 ]
Li, CC
机构
[1] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu, Taiwan
[2] Natl Taipei Univ Technol, Dept Mat & Mineral Resources Engn, Taipei, Taiwan
关键词
D O I
10.1111/j.1551-2916.2005.00858.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
To disperse nano-sized gamma-alumina powders in non-polar solvents, the surface of gamma-alumina has to be modified with unsaturated oleic acid, which forms aluminum-oleate on the surface. This changes the surface characteristics of gamma-alumina powders from hydrophilic to hydrophobic in nature. A colloidally stable gamma-alumina non-polar suspension is obtained when a critical amount of aluminum-oleate compound is formed on the surface. This is also evidenced by the results of adsorption and theoretical calculation of potential energies, which confirm the colloidal stability of organic gamma-alumina suspension caused by the steric repulsion mechanism.
引用
收藏
页码:882 / 887
页数:6
相关论文
共 28 条
[1]   Interaction of carboxylic acids with the oxyhydroxide surface of aluminium: poly(acrylic acid), acetic acid and propionic acid on pseudoboehmite [J].
Alexander, MR ;
Beamson, G ;
Blomfield, CJ ;
Leggett, G ;
Duc, TM .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2001, 121 (1-3) :19-32
[2]  
Barton A.F. M., 1991, CRC HDB SOLUBILITY P
[3]  
BARTON AFM, 1991, CRC HDB SOLUBILITY P, pCH13
[4]  
CALVERT PD, 1986, AM CERAM SOC BULL, V65, P669
[5]  
CHARTIER T, 1987, AM CERAM SOC BULL, V66, P1653
[6]  
ISRAELACHVILI J, 1991, INTERMOLECULAR SURFA, pCH11
[7]   Stabilization of aqueous BaTiO3 suspensions with ammonium salt of poly(acrylic acid) at various pH values [J].
Jean, JH ;
Wang, HR .
JOURNAL OF MATERIALS RESEARCH, 1998, 13 (08) :2245-2250
[8]   Redispersion and reactivity studies on surfactant-coated magnesium oxide nanoparticles [J].
Jeevanandam, P ;
Klabunde, KJ .
LANGMUIR, 2003, 19 (13) :5491-5495
[9]   Depletion flocculation in colloidal dispersions [J].
Jenkins, P ;
Snowden, M .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1996, 68 :57-96
[10]  
LEJA J, 1982, SURFACE CHEM FROTH F, P288