Nine-membered titanacyclic complexes based on an ethylene-bridged bis(phenolato) ligand: Synthesis, structure, and olefin polymerization activity

被引：133

作者：

Fokken, S

Spaniol, TP

Okuda, J

Sernetz, FG

Mulhaupt, R

机构：

[1] UNIV MAINZ,INST ANORGAN CHEM & ANALYT CHEM,D-55099 MAINZ,GERMANY

[2] UNIV FREIBURG,INST MAKROMOL CHEM,D-79104 FREIBURG,GERMANY

[3] UNIV FREIBURG,FREIBURGER MAT FORSCHUNGSZENTRUM,D-79104 FREIBURG,GERMANY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 20期

关键词：

D O I：

10.1021/om9704105

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetravalent titanium complexes containing the ethylene-linked bis(phenolato) ligand ebmp exhibit a C-2-symmetric conformation according to single-crystal X-ray structural analyses. In solution, a fluxional process equivalent to an enantiomerization is detected. Upon activation, with. methylaluminoxane, these complexes copolymerize ethylene and styrene with remarkably high incorporation of styrene.

引用

页码：4240 / 4242

页数：3

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