Spontaneous magnetization in the M[N(CN)2]2 (M = Cr, Mn) weak ferromagnets

被引：180

作者：

Manson, JL

Kmety, CR

Epstein, AJ

Miller, JS

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

[2] Ohio State Univ, Dept Phys, Columbus, OH 43210 USA

[3] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 11期

关键词：

D O I：

10.1021/ic9901259

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Octahedral M[N(CN)(2)](2) (M = Cr, Mn) have been prepared and exhibit a spontaneous magnetization below ordering temperatures of 47 and 16 K, respectively, due to a transition to a weak-ferromagnetic ground state. This is contrast to the ferromagnetic ordering observed for octahedral M[N(CN)(2)](2) (M = Co, Ni).

引用

收藏

页码：2552 / +

页数：3

相关论文

共 27 条

[11] DICYANAMIDE COMPLEXES OF COPPER(II), NICKEL(II) AND COBALT(II) WITH BENZIMIDAZOLE AND ITS 2-ALKYL-DERIVATIVES [J].

HVASTIJOVA, M ;

KOHOUT, J ;

OKRUHLICA, M ;

MROZINSKI, J ;

JAGER, L .

TRANSITION METAL CHEMISTRY, 1993, 18 (06) :579-582

[12] Structural isomers of M(dca)2 molecule-based magnets.: Crystal structure of tetrahedrally coordinated sheet-like β-Zn(dca)2 and β-Co/Zn(dca)2, and the octahedrally coordinated rutile-like α-Co(dca)2, where dca- = dicyanamide, N(CN)2-, and magnetism of β-Co(dca)2 [J].

Jensen, P ;

Batten, SR ;

Fallon, GD ;

Moubaraki, B ;

Murray, KS ;

Price, DJ .

CHEMICAL COMMUNICATIONS, 1999, (02) :177-178

[13]

KMETY CR, IN PRESS PHYS REV B

[14]

KMETY CR, UNPUB

[15] METAL PSEUDOHALIDES .27. STRUCTURES OF DICYANAMIDES OF BIVALENT 3D METALS M(N(CN)2)2 [J].

KOHLER, H ;

KOLBE, A ;

LUX, G .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1977, 428 (01) :103-112

[16] Hard magnets based on transition metal complexes with the dicyanamide anion, {N(CN)2}- [J].

Kurmoo, M ;

Kepert, CJ .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (12) :1515-1524

[17] Structure and magnetic properties of MnII[N(CN)2]2(pyrazine).: An antiferromagnet with an interpenetrating 3-D network structure [J].

Manson, JL ;

Incarvito, CD ;

Rheingold, AL ;

Miller, JS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (22) :3705-3706

[18] Crystal structure and magnetic properties of [Fe{N(CN)2}2(MeOH)2] a 2-D layered network consisting of hydrogen-bonded l-D chains [J].

Manson, JL ;

Arif, AM ;

Miller, JS .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (04) :979-983

[19] Structure and magnetic ordering of MII[N(CN)2]2 (M = Co, Ni) [J].

Manson, JL ;

Kmety, CR ;

Huang, QZ ;

Lynn, JW ;

Bendele, GM ;

Pagola, S ;

Stephens, PW ;

Liable-Sands, LM ;

Rheingold, AL ;

Epstein, AJ ;

Miller, JS .

CHEMISTRY OF MATERIALS, 1998, 10 (09) :2552-2560

[20] Interpenetrating three-dimensional rutile-like frameworks.: Crystal structure and magnetic properties of MnII[C(CN)3]2 [J].

Manson, JL ;

Campana, C ;

Miller, JS .

CHEMICAL COMMUNICATIONS, 1998, (02) :251-252