Complexation of titanium n-butoxide Ti(OBun)4 and zirconium n-butoxide Zr(OBun)4 with some oxime ligands and structural analysis of the complexes

被引：15

作者：

Buyuktas, BS ^{[1
]}

Aktas, O ^{[1
]}

机构：

[1] Akdeniz Univ, Dept Chem, TR-07058 Antalya, Turkey

来源：

TRANSITION METAL CHEMISTRY | 2006年 / 31卷 / 01期

关键词：

D O I：

10.1007/s11243-005-6324-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Titanium tetra-n-butoxide, Ti(OBun)(4), and zirconium tetra-n-butoxide, Zr(OBun)(4), were reacted with some wellknown dioxime and monoxime ligands such as dimethylglyoxime (DMG), salicylaldoxime ( SO) and acetone oxime (AO). The structures of the resulting complexes have been determined by elemental analysis, i. r. and H-1-n. m. r. spectroscopy. The complexation ratio of both Ti(OBun) 4 and Zr(OBun)(4) was found to be 1: 2 with DMG and SO. On the other hand, both 1: 1 and 1: 2 complexation ratios of the same metal alkoxides were observed with the ligand AO.

引用

页码：56 / 61

页数：6

共 22 条

[1]

AHSEN V, 1987, J CHEM SOC DA, V8, P1827

[2]

Basolo F., 1967, Mechanisms of Inorganic Reactions, pXi + 701

[3]

BRADLEY DC, 2001, ALKOXO ARYLOX DERIVA

[4] Spectroscopic characterization of oxime ligands and their complexes [J].