On the kinetics of catalytic reduction of nitrogen oxide by alkenes in oxidizing atmosphere

被引：4

作者：

Carniti, P ^{[1
]}

Gervasini, A ^{[1
]}

机构：

[1] Univ Milan, Dipartimento Chim Fis & Elettrochim, I-20133 Milan, Italy

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1999年 / 67卷 / 02期

关键词：

catalytic deNO(x); kinetic model; alkenes;

D O I：

10.1007/BF02475765

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A kinetic model is presented which considers the catalytic reduction of NO to N-2 by hydrocarbons in oxidizing atmosphere (NO-HC-O-2) as the sum of two simultaneous competitive reactions: the red-ox reaction between NO and hydrocarbon (NO-HC) and the hydrocarbon oxidation (O-2-HC). The model is developed for alkenes employed as reductants and noble metal catalysts. The ratio of the kinetic constants of the two reactions can be considered as a selectivity index in evaluating the ability of a catalyst to favor the desired NO reduction with respect to the undesired O-2-HC oxidation.

引用

页码：233 / 239

页数：7

共 7 条

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