Helical Twisting of Electrospun Liquid Crystalline Cellulose Micro- and Nanofibers

被引：85

作者：

Canejo, Joao P. ^{[1
]}

Borges, Joao P. ^{[1
]}

Godinho, M. Helena ^{[1
]}

Brogueira, Pedro ^{[4
,5
]}

Teixeira, Paulo I. C. ^{[2
,3
]}

Terentjev, Eugene M. ^{[6
]}

机构：

[1] Univ Nova Lisboa, Dept Ciencia Mat, P-2829516 Caparica, Portugal

[2] Inst Super Engn Lisboa, P-1950062 Lisbon, Portugal

[3] Univ Lisbon, Ctr Fis Teor & Computac, P-1649003 Lisbon, Portugal

[4] Inst Super Tecn, Dept Fis, P-1049001 Lisbon, Portugal

[5] Inst Super Tecn, Inst Ciencia & Engn Mat & Superficies, P-1049001 Lisbon, Portugal

[6] Univ Cambridge, Cavendish Lab, Cambridge CB3 OHE, England

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 24期

关键词：

D O I：

10.1002/adma.200801008

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Helically twisted fibers can be produced by electrospinning liquid-crystalline cellulose solutions. Fiber topographies are studied by atomic force microscopy, scanning electron microscopy (see figure) and polarized optical microscopy. The fibers have a nearly universal pitch-to-diameter ratio and comprise both right- and left-handed helices.

引用

页码：4821 / +

页数：6

共 22 条

[1]

ASADA T, 1998, MOL CRYST LIQ CRYST, V68, P1

[2]

Forces and extensions in semiflexible and rigid polymer chains and filaments [J].

Blundell, J. R. ;

Terentjev, E. M. .

JOURNAL OF PHYSICS A-MATHEMATICAL AND THEORETICAL, 2007, 40 (36) :10951-10964

[3]

PHASE-BEHAVIOR OF THE QUASI-TERNARY SYSTEM N-METHYLMORPHOLINE-N-OXIDE, WATER, AND CELLULOSE [J].

CHANZY, H ;

NAWROT, S ;

PEGUY, A ;

SMITH, P ;

CHEVALIER, J .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1982, 20 (10) :1909-1924

[4]

GILBERT RD, 2005, POLYSACCHARIDES STRU, P1179

[5]

Atomic force microscopy study of hydroxypropylcellulose films prepared from liquid crystalline aqueous solutions [J].

Godinho, MH ;

Fonseca, JG ;

Ribeiro, AC ;

Melo, LV ;

Brogueira, P .

MACROMOLECULES, 2002, 35 (15) :5932-5936

[6]

Direct fabrication of twisted nanofibers by electrospinning [J].

Gu, Bon Kang ;

Shin, Min Kyoon ;

Sohn, Ki Won ;

Kim, Sun I. ;

Kim, Seon Jeong ;

Kim, Sung-Kyoung ;

Lee, Haiwon ;

Park, Joon Shik .

APPLIED PHYSICS LETTERS, 2007, 90 (26)

[7]

Atomic force microscopy and transmission electron microscopy of cellulose from Micrasterias denticulata; evidence for a chiral helical microfibril twist [J].

Hanley, SJ ;

Revol, JF ;

Godbout, L ;

Gray, DG .

CELLULOSE, 1997, 4 (03) :209-220

[8]

A review on polymer nanofibers by electrospinning and their applications in nanocomposites [J].

Huang, ZM ;

Zhang, YZ ;

Kotaki, M ;

Ramakrishna, S .

COMPOSITES SCIENCE AND TECHNOLOGY, 2003, 63 (15) :2223-2253

[9]

Structural studies of electrospun cellulose nanofibers [J].

Kim, Choo-Won ;

Kim, Dae-Sik ;

Kang, Seung-Yeon ;

Marquez, Manuel ;

Joo, Yong Lak .

POLYMER, 2006, 47 (14) :5097-5107

[10]

Spatial persistence of angular correlations in amyloid fibrils [J].

Knowles, Tuomas P. J. ;

Smith, Jeffrey F. ;

Craig, Aidan ;

Dobson, Christopher M. ;

Welland, Mark E. .

PHYSICAL REVIEW LETTERS, 2006, 96 (23)

← 1 2 3 →