Characterization of soda hardwood lignin and the formation of lignin fibers by melt spinning

被引:47
作者
Awal, Abdul [1 ]
Sain, Mohini [1 ]
机构
[1] Univ Toronto, Ctr Biocomposites & Biomat Proc, Toronto, ON M5S 3B3, Canada
关键词
biopolymers and renewable polymers; blends; fibers; rheology; CARBON-FIBERS; ACID; SOFTWOOD;
D O I
10.1002/app.38911
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
Lignin fibers were developed from a commercial available soda hardwood lignin (SHL) with a melt-spinning approach. SHL showed spinnability to form the fine fibers when poly(ethylene oxide) was used as a plasticizer with lignin. The thermal properties of lignin provided valuable information to assist the processing steps of the lignin fiber formation. The guaiacyl/syringyl ratio in SHL was determined by 31P-NMR because it had great influence on the thermal mobility of lignin. A suitable temperature profile for the melt spinning was predicted through rheological studies of lignin. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
引用
收藏
页码:2765 / 2771
页数:7
相关论文
共 25 条
[1]
Short nylon fibre reinforced PP: Melt rheology [J].
Abraham, Thomas N. ;
George, K. E. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2007, 46 (03) :321-325
[2]
[Anonymous], 1993, WOOD CHEM, DOI DOI 10.1016/B978-0-08-092589-9.50005-X
[3]
QUANTITATIVE P-31 NMR ANALYSIS OF 6 SOLUBLE LIGNINS [J].
ARGYROPOULOS, DS .
JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 1994, 14 (01) :65-82
[4]
Spectroscopic Studies and Evaluation of Thermorheological Properties of Softwood and Hardwood Lignin [J].
Awal, Abdul ;
Sain, Mohini .
JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 122 (02) :956-963
[5]
Baker F. S., 2007, FY 2007 PROGR REPORT
[6]
Bocchini P, 1996, RAPID COMMUN MASS SP, V10, P1144, DOI 10.1002/(SICI)1097-0231(19960715)10:9<1144::AID-RCM614>3.0.CO
[7]
2-3
[8]
LIGNIN POLYMER SYSTEMS AND SOME APPLICATIONS [J].
FELDMAN, D .
PROGRESS IN POLYMER SCIENCE, 1986, 12 (04) :271-&
[9]
Glasser W.G., 1989, Lignin: Properties and materials
[10]
Goring D. A. I., 1989, LIGNIN PROPERTIES MA