Mesoporous Metallic Cells: Design of Uniformly Sized Hollow Mesoporous PtRu Particles with Tunable Shell Thicknesses

被引:164
作者
Ataee-Esfahani, Hamed [1 ,2 ]
Liu, Jian [3 ]
Hu, Ming [1 ]
Miyamoto, Nobuyoshi [4 ]
Tominaka, Satoshi [1 ]
Wu, Kevin C. W. [5 ]
Yamauchi, Yusuke [1 ,2 ]
机构
[1] Natl Inst Mat Sci, World Premier Int WPI Res Ctr Mat Nanoarchitechto, Tsukuba, Ibaraki 3050044, Japan
[2] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan
[3] Univ Queensland, Australian Inst Bioengn & Nanotechnol, ARC Ctr Excellence Funct Nanomat, St Lucia, Qld 4072, Australia
[4] Fukuoka Inst Technol, Dept Life Environm & Mat Sci, Higashi Ku, Fukuoka 8110295, Japan
[5] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan
关键词
mesoporous materials; hollow structures; metal particles; alloys; electrocatalysts; SURFACTANT ADSORPTION; NONIONIC SURFACTANTS; PLATINUM FILMS; SPHERES; SILICA; NANOPARTICLES; TITANIA; CORE;
D O I
10.1002/smll.201202539
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A new class of hollow mesoporous Pt-Ru and Pt particles with uniform size, named 'mesoporous metallic cells', are synthesized through a dual-templating approach using colloidal silica particles and non-ionic surfactants. To realize the full potential of mesoporous metals as electrocatalysts, the shell thicknesses, compositions, and hollow cavity sizes are precisely controlled. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1047 / 1051
页数:5
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