Facile growth of hexagonal NiO nanoplatelet arrays assembled by mesoporous nanosheets on Ni foam towards high-performance electrochemical capacitors

被引:58
作者
Yuan, Changzhou [1 ]
Li, Jiaoyang [1 ]
Hou, Linrui [1 ]
Yang, Long [1 ]
Shen, Laifa [2 ]
Zhang, Xiaogang [2 ]
机构
[1] Anhui Univ Technol, Sch Mat & Engn, Maanshan 243002, Peoples R China
[2] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Jiangsu, Peoples R China
基金
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词
Nickel oxide nanoplatelet arrays; Nickel foam; Mesoporous; Electrochemical capacitors; CO3O4 NANOWIRE ARRAYS; NICKEL-OXIDE; CARBON NANOTUBES; ENERGY-STORAGE; SUPERCAPACITORS; ELECTRODES; TEMPLATE; ROUTE;
D O I
10.1016/j.electacta.2012.06.044
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In the work, we develop a novel two-step strategy to synthesize self-supported hexagonal nickel oxide nanoplatelet arrays on Ni foam: precipitating hydroxides followed by calcinating process. These nanoplatelets are composed of a multilayer of ultrathin mesoporous NiO nanosheets. The unique Ni foam-supported mesoporous NiO nanoplatelet arrays electrode promises fast ion and electron transport, large electroactive surface area, and excellent structural stability. As a result, superior pseudocapacitive performance is achieved with large specific capacitance in the range of 1124-864 F g(-1) and excellent cycling stability up to 5000 cycles, suggesting their promising application for electrochemical capacitors. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:532 / 538
页数:7
相关论文
共 32 条
[1]   Preparation of mesoporous nanocrystalline Co3O4 and its applicability of porosity to the formation of electrochemical capacitance [J].
Cao, L ;
Lu, M ;
Li, HL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (05) :A871-A875
[2]   Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes [J].
Futaba, Don N. ;
Hata, Kenji ;
Yamada, Takeo ;
Hiraoka, Tatsuki ;
Hayamizu, Yuhei ;
Kakudate, Yozo ;
Tanaike, Osamu ;
Hatori, Hiroaki ;
Yumura, Motoo ;
Iijima, Sumio .
NATURE MATERIALS, 2006, 5 (12) :987-994
[3]   Electrochemical capacitance of Co3O4 nanowire arrays supported on nickel foam [J].
Gao, Yinyi ;
Chen, Shuli ;
Cao, Dianxue ;
Wang, Guiling ;
Yin, Jinling .
JOURNAL OF POWER SOURCES, 2010, 195 (06) :1757-1760
[4]   How to achieve maximum utilization of hydrous ruthenium oxide for supercapacitors [J].
Hu, CC ;
Chen, WC ;
Chang, KH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (02) :A281-A290
[5]   Design and tailoring of the nanotubular arrayed architecture of hydrous RuO2 for next generation supercapacitors [J].
Hu, Chi-Chang ;
Chang, Kuo-Hsin ;
Lin, Ming-Champ ;
Wu, Yung-Tai .
NANO LETTERS, 2006, 6 (12) :2690-2695
[6]  
Kinoshita K., 1988, CARBON ELECTROCHEMIC, P326
[7]   Facile approach to prepare loose-packed NiO nano-flakes materials for supercapacitors [J].
Lang, Jun-Wei ;
Kong, Ling-Bin ;
Wu, Wei-Jin ;
Luo, Yong-Chun ;
Kang, Long .
CHEMICAL COMMUNICATIONS, 2008, (35) :4213-4215
[8]   Nanosheets based mesoporous NiO microspherical structures via facile and template-free method for high performance supercapacitors [J].
Lee, Jeong Woo ;
Ahn, Taebin ;
Kim, Jong Hun ;
Ko, Jang Myoun ;
Kim, Jong-Duk .
ELECTROCHIMICA ACTA, 2011, 56 (13) :4849-4857
[9]   An ordered mesoporous carbon with short pore length and its electrochemical performances in supercapacitor applications [J].
Li, Hui-Qiao ;
Luo, Jia-Yan ;
Zhou, Xu-Feng ;
Yu, Cheng-Zhong ;
Xia, Yong-Yao .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (08) :A731-A736
[10]   Single-crystalline Ni(OH)2 and NiO nanoplatelet arrays as supercapacitor electrodes [J].
Li, Jiangtian ;
Zhao, Wei ;
Huang, Fuqiang ;
Manivannan, Ayyakkannu ;
Wu, Nianqiang .
NANOSCALE, 2011, 3 (12) :5103-5109