Crosslinking and drying of a two-component waterborne coating monitored by a functionalized charge-transfer fluorescence probe

被引:11
作者
Verhey, HJ
Bekker, CHW
Verhoeven, JW
vanderVen, LGJ
Hofstraat, JW
机构
[1] UNIV AMSTERDAM,DEPT ORGAN CHEM,NL-1018 WS AMSTERDAM,NETHERLANDS
[2] AKZO NOBEL CENT RES,NL-6800 SB ARNHEM,NETHERLANDS
关键词
ceto-acetate functionalization; film formation; polyacrylate dispersion;
D O I
10.1016/S0032-3861(96)01052-X
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A donor-bridge-acceptor fluorophore with extreme sensitivity to environmental influences has been attached covalently to a polyamino crosslinker. It was found that the progress of the crosslinking reaction with an aceto-acetate functionalized polyacrylate dispersion can be monitored from the fluorescence wavelength shift of the fluorophore. Also formation and drying of films applied from the resulting labelled dispersion induces a significant wavelength shift of the fluorescence of the incorporated label. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:4491 / 4497
页数:7
相关论文
共 16 条
[1]   DEVELOPMENT OF COHESIVE STRENGTH IN POLYMER-FILMS FROM LATTICES - EFFECT OF POLYMER-CHAIN INTERDIFFUSION AND CROSS-LINKING [J].
DANIELS, ES ;
KLEIN, A .
PROGRESS IN ORGANIC COATINGS, 1991, 19 (04) :359-378
[2]   Analytical aspects and film properties of two-pack acetoacetate functional latexes [J].
Geurink, PJA ;
vanDalen, L ;
vanderVen, LGJ ;
Lamping, RR .
PROGRESS IN ORGANIC COATINGS, 1996, 27 (1-4) :73-78
[3]   SYSTEMATIC STUDY OF A SERIES OF HIGHLY FLUORESCENT ROD-SHAPED DONOR-ACCEPTOR SYSTEMS [J].
HERMANT, RM ;
BAKKER, NAC ;
SCHERER, T ;
KRIJNEN, B ;
VERHOEVEN, JW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (03) :1214-1221
[4]  
JENNESKENS LW, 1992, RECL TRAV CHIM PAY B, V111, P507
[5]   INTRAMOLECULAR CHARGE-TRANSFER FLUORESCENCE OF 1-PHENYL-4-(4-CYANO-1-NAPHTHYLMETHYLENE)-PIPERIDINE IN BINARY-MIXTURES OF ALPHA,OMEGA-DIACETYLPOLY(ETHYLENE GLYCOL)-1000 AND ALPHA,OMEGA-DIACETYLPOLY(ETHYLENE GLYCOL)-3000 - PREFERENTIAL SOLVATION IN THE SOLID-STATE [J].
JENNESKENS, LW ;
VERHEY, HJ ;
VANRAMESDONK, HJ ;
VERHOEVEN, JW .
MACROMOLECULES, 1992, 25 (23) :6365-6367
[6]   INTRAMOLECULAR CHARGE-TRANSFER FLUORESCENCE OF 1-PHENYL-4-[(4-CYANO-1-NAPHTHYL)METHYLENE]PIPERIDINE AS A MORPHOLOGY PROBE IN ALPHA,OMEGA-DIACETYLPOLY(ETHYLENE GLYCOL) MATRICES [J].
JENNESKENS, LW ;
VERHEY, HJ ;
VANRAMESDONK, HJ ;
WITTEVEEN, AJ ;
VERHOEVEN, JW .
MACROMOLECULES, 1991, 24 (14) :4038-4040
[7]  
JENNESKENS LW, 1991, APPL FLUOR TECHNOL, V3, P11
[9]   EXCITED-STATE DIPOLE-MOMENT AND SOLVATOCHROMISM OF HIGHLY FLUORESCENT ROD-SHAPED BICHROMOPHORIC MOLECULES [J].
MES, GF ;
DEJONG, B ;
VANRAMESDONK, HJ ;
VERHOEVEN, JW ;
WARMAN, JM ;
DEHAAS, MP ;
HORSMANVANDENDOOL, LEW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) :6524-6528
[10]   FOLLOWING POLYMERIZATION KINETICS OF MULTIFUNCTIONAL ACRYLATES IN REAL-TIME BY FLUORESCENCE PROBE METHODOLOGY [J].
PACZKOWSKI, J ;
NECKERS, DC .
MACROMOLECULES, 1992, 25 (02) :548-553