Photoelectron scattering effects in molecular photoionization

被引:23
作者
Gessner, O [1 ]
Heiser, F [1 ]
Cherepkov, NA [1 ]
Zimmermann, B [1 ]
Becker, U [1 ]
机构
[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
关键词
angular distributions of photoelectrons and photoions; photoelectron-photoion coincidence spectroscopy; photoelectron scattering; CO molecule;
D O I
10.1016/S0368-2048(98)00421-6
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
An angle-resolved photoelectron-photoion coincidence experiment has been performed on CO at a photon energy of 321 eV. Complete, three-dimensional fragment ion angular distributions for several C(1s) photoelectron emission directions have been measured. For the case of photoelectron emission along the light polarization vector, the ionic fragment angular distribution has been compared to model calculations to gain information about the relative phase shift between sigma-->sigma and sigma-pi transition matrix elements. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:113 / 118
页数:6
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