Evidence for a common Ru(P)(NO)2 intermediate in photochemical and synthesis pathways involving Ru(TmTP)(NO)(ONO) and excess nitric oxide

被引：13

作者：

Lorkovic, IM ^{[1
]}

Ford, PC ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 13期

关键词：

D O I：

10.1039/a901779h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optical and IR spectra of the intermediate formed from the reaction of Ru(CO)(TmTP) with NO are compared with transient UV-VIS and FTIR spectra of photochemical intermediates formed from the photolysis and recovery of Ru(TmTP)(NO)(ONO) in the presence of NO; comparison reveals that the two pathways share a common intermediate, which IR spectral properties suggest to be trans-Ru(TmTP)(NO)(2).

引用

页码：1225 / 1226

页数：2

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