Organo-scandium and -yttrium complexes supported by a salicylaldiminato ligand

被引：67

作者：

Emslie, DJH

Piers, WE

MacDonald, R

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ Alberta, Dept Chem, Xray Struct Lab, Edmonton, AB T6G 2G2, Canada

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 03期

关键词：

D O I：

10.1039/b108336h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of a salicylaldiminato ligand with M(CH2-SiMe2Ph)(3)(THF)(2) (M = Sc, Y) leads to diastereoselective formation of highly thermally stable L2MR complexes whose reactivity with dihydrogen to form Group 3 metal hydrides is described.

引用

页码：293 / 294

页数：2

共 17 条

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