Electrolytic partial fluorination of organic compounds. Part 37: Selective electrolytic fluorination of dimethoxyethane, diethylene glycol dimethyl ether, and crown ethers

被引：13

作者：

Hou, YK ^{[1
]}

Fuchigami, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(99)01627-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The anodic fluorination of dimethoxyethane (DME) and diethylene glycol dimethyl ether in acetonitrile containing a fluoride salt provided moderate yields of the corresponding monofluoromethyl ethers. The anodic fluorination of crown ethers resulted in carbon-carbon bond cleavage which led to the selective production of alpha,omega-difluoro products with high yields. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：7819 / 7822

页数：4

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