Aqua(hexacyanoferrato-N)bis(mu-glycine)-glycinecerium(III) monohydrate

被引:17
作者
GarciaGranda, S [1 ]
Morales, AD [1 ]
Ruiz, ER [1 ]
Bertran, JF [1 ]
机构
[1] CTR NACL INVEST CIENT,DIRECC QUIM,HAVANA,CUBA
关键词
D O I
10.1107/S0108270196003149
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of the title compound, [Ce{Fe(CN)(6)}-(C2H5NO2)(3)(H2O)].H2O, consists of FeC6 octahedra linked to an eight-coordinate cerium ion via two cyanide bridging Ce-N-C-Fe groups, The rest of the coordination polyhedron of the cerium is formed by six O atoms: one from a molecule of water and five from glycine molecules, The three-dimensional framework is formed through N-H ... N and O-H ... N hydrogen-bonding interactions. Two glycine molecules form bifurcated hydrogen bonds, An additional uncoordinated molecule of water is within hydrogen-bonding distance of two glycine molecules.
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页码:1679 / 1681
页数:3
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