'Living' macrolactonisation: Thermodynamically-controlled cyclisation and interconversion of oligocholates

被引：123

作者：

Brady, PA ^{[1
]}

BonarLaw, RP ^{[1
]}

Rowan, SJ ^{[1
]}

Suckling, CJ ^{[1
]}

Sanders, JKM ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CTR MOLEC RECOGNIT,CAMBRIDGE CB2 1EW,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 03期

关键词：

D O I：

10.1039/cc9960000319

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclocholates are efficiently and rapidly synthesised from suitable monomers by transesterification under thermodynamic, equilibrating conditions using a potassium methoxide-crown ether complex.

引用

页码：319 / 320

页数：2

共 23 条

[1] CONDENSATION OF TETRAALDEHYDES WITH PYRROLE - DIRECT SYNTHESIS OF CAPPED PORPHYRINS
ALMOG, J
BALDWIN, JE
DYER, RL
PETERS, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (01) : 226 - 227
[2] EXPANDING ROLES FOR TEMPLATES IN SYNTHESIS
ANDERSON, S
ANDERSON, HL
SANDERS, JKM
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (09) : 469 - 475
[3] 8-MEMBERED AND HIGHER-MEMBERED RING COMPOUNDS .6. CIS-DI-ORTHO-THYMOTIDES AND TRI-O-THYMOTIDES
BAKER, W
GILBERT, B
OLLIS, WD
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1952, (APR): : 1443 - 1446
[4] PROTON-TRANSFER STEPS IN STEGLICH ESTERIFICATION - A VERY PRACTICAL NEW METHOD FOR MACROLACTONIZATION
BODEN, EP
KECK, GE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (13) : 2394 - 2395
[5] CYCLOCHOLATES - SYNTHESIS AND ION BINDING
BONARLAW, RP
SANDERS, JKM
[J]. TETRAHEDRON LETTERS, 1992, 33 (15) : 2071 - 2074
[6] POLYOL RECOGNITION BY A STEROID-CAPPED PORPHYRIN - ENHANCEMENT AND MODULATION OF MISFIT GUEST BINDING BY ADDED WATER OR METHANOL
BONARLAW, RP
SANDERS, JKM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) : 259 - 271
[7] MORPHINE RECOGNITION BY A PORPHYRIN CYCLOCHOLATE MOLECULAR BOWL
BONARLAW, RP
MACKAY, LG
SANDERS, JKM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (05) : 456 - 458
[8] TRANSLACTONIZATION ROUTE TO MACROCYCLIC LACTONES
COREY, EJ
BRUNELLE, DJ
NICOLAOU, KC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (22) : 7359 - 7360
[9] CHOLAPHANES ET-AL - STEROIDS AS STRUCTURAL COMPONENTS IN MOLECULAR ENGINEERING
DAVIS, AP
[J]. CHEMICAL SOCIETY REVIEWS, 1993, 22 (04) : 243 - 253
[10] DHAWAN B, 1987, MAKROMOL CHEM, V188, P921

← 1 2 3 →