Self-assembly of monopyrazolylporphyrins by hydrogen bonding in solution

被引：54

作者：

Ikeda, C ^{[1
]}

Nagahara, N ^{[1
]}

Motegi, E ^{[1
]}

Yoshioka, N ^{[1
]}

Inoue, H ^{[1
]}

机构：

[1] Keio Univ, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904513i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-associated structures of two noble meso-(monopyrazolyltritolyl)porphyrins synthesized via their NH-protected precursors have been studied by H-1 NMR, FT-IR and ESI MS measurements; meso-(pyrazol-4-yl)porphyrin and meso-(3,5-dimethylpyrazol-4-yl)porphyrin form a dimer and a tetramer, respectively, in solution due to intermolecular hydrogen bonding between pyrazole units.

引用

页码：1759 / 1760

页数：2

共 27 条

[1] HYDROGEN BONDING OF PYRAZOLE IN CARBON TETRACHLORIDE SOLUTION [J].

ANDERSON, DM ;

DUNCAN, JL ;

ROSSOTTI, FJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (JAN) :140-&

[2] DYNAMIC INTERMOLECULAR TAUTOMERISM OF 3,5-DIMETHYLPYRAZOLE IN THE SOLID-STATE BY C-13 CP/MAS NMR-SPECTROSCOPY AND X-RAY CRYSTALLOGRAPHY [J].

BALDY, A ;

ELGUERO, J ;

FAURE, R ;

PIERROT, M ;

VINCENT, EJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (18) :5290-5291

[3] Hydrogen-bonded porphyrinic solids: Supramolecular networks of octahydroxy porphyrins [J].

Bhyrappa, P ;

Wilson, SR ;

Suslick, KS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (36) :8492-8502

[4]

CHAN AC, 1984, J CHEM SOC P1, P1483

[5]

Connors K. A., 1987, BINDING CONSTANTS

[6] INDUCTION OF PEPTIDE CONFORMATION AT APOLAR WATER INTERFACES .1. A STUDY WITH MODEL PEPTIDES OF DEFINED HYDROPHOBIC PERIODICITY [J].

DEGRADO, WF ;

LEAR, JD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) :7684-7689

[7] Self-assembly of a multi-porphyrin supramolecular macrocycle by hydrogen bond molecular recognition [J].

Drain, CM ;

Russell, KC ;

Lehn, JM .

CHEMICAL COMMUNICATIONS, 1996, (03) :337-338

[8]

DUCHARME Y, 1988, J ORG CHEM, V53, P5789

[9] PROTON-TRANSFER IN SOLID HETEROCYCLES - AN X-RAY AND CPMAS NMR-STUDY [J].

ELGUERO, J ;

CANO, FH ;

FOCESFOCES, C ;

LLAMASSAIZ, AL ;

LIMBACH, HH ;

AGUILARPARRILLA, F ;

CLARAMUNT, RM ;

LOPEZ, C .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1994, 31 (03) :695-700

[10] Synthesis and properties of cyclic ruthenium(II) porphyrin tetramers [J].

Funatsu, K ;

Imamura, T ;

Ichimura, A ;

Sasaki, Y .

INORGANIC CHEMISTRY, 1998, 37 (08) :1798-1804

← 1 2 3 →