Synthesis and properties of a new kinetically stabilized digermyne: New insights for a germanium analogue of an alkyne

被引：167

作者：

Sugiyama, Y

Sasamori, T

Hosoi, Y

Furukawa, Y

Takagi, N

Nagase, S

Tokitoh, N ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

[2] Waseda Univ, Sch Sci & Engn, Dept Chem, Shinjyuku Ku, Tokyo 1698555, Japan

[3] Inst Mol Sci, Dept Theoret Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 03期

关键词：

D O I：

10.1021/ja057205y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of an overcrowded (E)-1,2-dibromodigermene, Bbt(Br)Ge=Ge(Br)Bbt (2) [Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl], with KC8 afforded a stable digermyne, BbtGe GeBbt (1). The Ge Ge triple-bond characters of 1 were revealed by the X-ray crystallographic analysis and spectroscopic studies (UV/vis and Raman spectra) together with theoretical calculations. The Ge Ge bond lengths of the two nonidentical molecules of 1 observed in the unit cell were shorter than that of the previously reported digermyne, Ar'Ge GeAr' (Ar' = 2,6-Dip(2)C(6)H(3), Dip = 2,6-diisopropylphenyl).

引用

页码：1023 / 1031

页数：9

共 84 条

[1]

Baines K. M., 1996, ADV ORGANOMET CHEM, V39, P275, DOI DOI 10.1016/S0065-3055(08)60470-0

[2] TETRAMESITYLGERMASILENE - THE 1ST RELATIVELY STABLE GERMASILENE AND ITS REARRANGEMENT TO A SILYLGERMYLENE [J].