Electron spin transition solution applicable to an ensemble of isolated electrons

被引:2
作者
Boyd, JK [1 ]
机构
[1] Univ Calif Lawrence Livermore Natl Lab, Livermore, CA 94551 USA
关键词
electron spin resonance; ESR; electron spin transition; analytic electron spin solution; fermion spin transition; rotating wave approximation;
D O I
10.1006/jmre.1999.1770
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
An electron spin aligned with a static magnetic field changes its orientation when subjected to a time-varying magnetic field which is directed perpendicular to the static magnetic field. This well-known phenomenon is readily calculated when the time-varying magnetic field is circularly polarized; however, the evolution of the spin-state wavefunctions becomes much more difficult to calculate when the time-varying magnetic field is linearly polarized. For linear polarization and isolated spins, an analytic solution has been derived for the dynamical spin-state wavefunctions. Part of the solution procedure relies on an expansion using a small parameter, which is the ratio of the amplitude of the time-varying magnetic field to the static magnetic field. To verify the validity of the expansion technique, a numerical solution of the basic equations is compared to the analytic solution. Results are found to agree to better than 10% for exact resonance and better than 5% in general. (C) 1999 Academic Press.
引用
收藏
页码:109 / 125
页数:17
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