Direct insertion of polypyrrole into molybdenum disulfide

被引：34

作者：

Bissessur, R ^{[1
]}

Liu, PKY ^{[1
]}

机构：

[1] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada

来源：

SOLID STATE IONICS | 2006年 / 177卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

polypyrrole; molybdenum disulfide; intercalation;

D O I：

10.1016/j.ssi.2005.09.052

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, we report on the direct intercalation of polypyrrole into MoS2. This was achieved by first synthesizing LiMoS2. The LiMoS2 was exfoliated by reaction with deionized water. Addition of a colloidal Suspension of polypyrrole in NMF to the single MoS, layers results in flocculation with entrapment of the polymer chain in the van der Waals gap of the layered structure. The sandwiched compound was characterized by powder X-ray diffraction, thermogravimetric analysis and differential scanning calorimetry. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：191 / 196

页数：6

共 38 条

[1]

BEIN T, 1989, SYNTHETIC MET, V29, pE163

[2] Intercalation chemistry of molybdenum disulfide [J].

Benavente, E ;

Santa Ana, MA ;

Mendizábal, F ;

González, G .

COORDINATION CHEMISTRY REVIEWS, 2002, 224 (1-2) :87-109

[3] INCLUSION OF POLY(ANILINE) INTO MOO3 [J].

BISSESSUR, R ;

DEGROOT, DC ;

SCHINDLER, JL ;

KANNEWURF, CR ;

KANATZIDIS, MG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) :687-689

[4] Novel pyrene and 8-anilino-1-naphthalenesulfonic acid-MoS2 intercalates [J].

Bissessur, R ;

Wagner, BD .

JOURNAL OF MATERIALS SCIENCE, 2004, 39 (01) :119-125

[5] Intercalation of tetraazamacrocycles into molybdenum disulfide [J].

Bissessur, R ;

Haines, RI ;

Brüning, R .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (01) :44-49

[6] Intercalation of a pendant-arm tetraazamacrocycle into molybdenum disulfide [J].

Bissessur, R ;

Haines, RI ;

Hutchings, DR ;

Brüning, R .

CHEMICAL COMMUNICATIONS, 2001, (17) :1598-1599

[7] Toward pillared layered metal sulfides. Intercalation of the chalcogenide clusters Co(6)Q(8)(PR(3))(6) (Q=S, Se, and Te and R=alkyl) into MoS2 [J].

Bissessur, R ;

Heising, J ;

Hirpo, W ;

Kanatzidis, M .

CHEMISTRY OF MATERIALS, 1996, 8 (02) :318-&

[8] ENCAPSULATION OF POLYMERS INTO MOS2 AND METAL TO INSULATOR TRANSITION IN METASTABLE MOS2 [J].

BISSESSUR, R ;

KANATZIDIS, MG ;

SCHINDLER, JL ;

KANNEWURF, CR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (20) :1582-1585

[9]

BISSESSUR R, 1994, MOL CRYST LIQ CRYS A, V244, pA249

[10] Microstructural characterization of highly HDS-active Co6S8-pillared molybdenum sulfides [J].

Brenner, J ;

Marshall, CL ;

Ellis, L ;

Tomczyk, N ;

Heising, J ;

Kanatzidis, M .

CHEMISTRY OF MATERIALS, 1998, 10 (05) :1244-1257

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