Synthesis and structures of new salen complexes with bulky groups

被引：32

作者：

Dyers, L

Que, SY

VanDerveer, D

Bu, XR

机构：

[1] Clark Atlanta Univ, Dept Chem, Atlanta, GA 30314 USA

[2] NIEHS, Free Rad Metab Sect, Lab Pharmacol & Chem, Res Triangle Pk, NC 27709 USA

[3] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 01期

基金：

美国国家卫生研究院; 美国国家航空航天局;

关键词：

Schiff base ligand; salen; nickel complex; copper complex; palladium complex; iron complex; crystal structure;

D O I：

10.1016/j.ica.2005.06.068

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new series of Schiff base complexes [Fe(III), VO(II), Pd(II), Cu(II), and Ni(II)] has been developed. The ligand possesses bulky t-pentyl groups at the 3- and 5-positions. The iron (III) complex is obtained in monomeric form with a square-pyramidal configuration while the copper complex is with square-planar configuration. (c) 2005 Elsevier B.V. All rights reserved.

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收藏

页码：197 / 203

页数：7

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