Enhanced storage property of LiNi0.8Co0.15Al0.05O2 coated with LiCoO2

被引：73

作者：

Liu, Wanmin ^{[1
,2
]}

Hu, Guorong ^{[2
]}

Du, Ke ^{[2
]}

Peng, Zhongdong ^{[2
]}

Cao, Yanbing ^{[2
]}

机构：

[1] Hunan Inst Engn, Sch Chem & Chem Engn, Xiangtan 411104, Peoples R China

[2] Cent S Univ, Sch Met Sci & Engn, Changsha 410083, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2013年 / 230卷

关键词：

Lithium-ion battery; Nickel-rich cathode material; Lithium cobalt oxide; Storage property; LITHIUM-ION BATTERIES; LINI0.8CO0.2O2 CATHODE MATERIALS; ELECTROCHEMICAL PROPERTIES; RECHARGEABLE BATTERIES; ELECTRODE MATERIALS; AL; IMPROVEMENT; LINIO2; CELLS; CO2;

D O I：

10.1016/j.jpowsour.2012.12.065

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The storage properties of LiNi0.8Co0.15Al0.05O2 and LiCoO2-coated LiNi0.8Co0.15Al0.05O2 have been investigated comparatively. It is found that the latter exhibits better storage stability than the former. After storage in air at different relative humidities, LiCoO2-coated LiNi0.8Co0.15Al0.05O2 shows little changes in the aspects of weight, nickel oxidation state, moisture and carbon contents and electrochemical performance. However, for LiNi0.8Co0.15Al0.05O2, the higher the air humidity is, the bigger these aspects change. Fourier transformed infrared (FTIR) spectrum reveals that LiCoO2-coated LiNi0.8Co0.15Al0.05O2 is resistant to H2O and CO2 in air. X-ray photoelectron spectroscopy gives evidence that the LiCoO2 coating layer suppresses effectively the reactions between LiNi0.8Co0.15Al0.05O2 and atmosphere, which contributes to the enhancement of storage performance of LiCoO2-coated LiNi0.8Co0.15Al0.05O2. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：201 / 206

页数：6

共 47 条

[1] Surface characterization of electrodes from high power lithium-ion batteries [J].

Andersson, AM ;

Abraham, DP ;

Haasch, R ;

MacLaren, S ;

Liu, J ;

Amine, K .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (10) :A1358-A1369

[2] Preparation of spherical LiNi0.80Co0.15Mn0.05O2 lithium-ion cathode material by continuous co-precipitation [J].

Cheralathan, K. K. ;

Kang, Na Young ;

Park, Hun Su ;

Lee, You Jin ;

Choi, Won Choon ;

Ko, Young Soo ;

Park, Yong-Ki .

JOURNAL OF POWER SOURCES, 2010, 195 (05) :1486-1494

[3] Significant Improvement of LiNi0.8Co0.15Al0.05O2 Cathodes at 60°C by SiO2 Dry Coating for Li-Ion Batteries [J].

Cho, Yonghyun ;

Cho, Jaephil .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (06) :A625-A629

[4] LiNi0.8Co0.15Al0.05O2 cathode materials prepared by TiO2 nanoparticle coatings on Ni0.8Co0.15Al0.05(OH)2 Precursors [J].

Cho, Younghyun ;

Lee, Yong-Seok ;

Park, Seul-A ;

Lee, Youngil ;

Cho, Jaephil .

ELECTROCHIMICA ACTA, 2010, 56 (01) :333-339

[5] Cathodic behavior of (Co, Ti, Mg)-doped LiNiO2 [J].

Chowdari, BVR ;

Rao, GVS ;

Chow, SY .

SOLID STATE IONICS, 2001, 140 (1-2) :55-62

[6] Effect of Mg2+ doping on the structural, thermal, and electrochemical properties of LiNi0.8Co0.16Mg0.04O2 [J].

D'Epifanio, A ;

Croce, F ;

Ronci, F ;

Albertini, VR ;

Traversa, E ;

Scrosati, B .

CHEMISTRY OF MATERIALS, 2004, 16 (18) :3559-3564

[7] Synthesis and characterisation of LiNi1-x-yCoxAlyO2cathodes for lithium-ion batteries by the PVA precursor method [J].

Duvigneaud, PH ;

Segato, T .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2004, 24 (06) :1375-1380

[8] Storage characteristics of LiNi0.8Co0.1+xMn0.1-xO2 (x=0, 0.03, and 0.06) cathode materials for lithium batteries [J].

Eom, Junho ;

Kim, Min Gyu ;

Cho, Jaephil .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (03) :A239-A245

[9] Dependence of electrochemical Behavior on concentration and annealing temperature of LixCoPO4 phase-grown LiNi0.8Co0.16Al0.04O2 cathode materials [J].

Eom, Junho ;

Ryu, Kwang Sun ;

Cho, Jaephil .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (03) :A228-A233

[10] Nickel oxyhydroxides with various oxidation states prepared by chemical oxidation of spherical β-Ni(OH)2 [J].

Fu, Xian-Zhu ;

Zhu, Ying-Jie ;

Xu, Qing-Chi ;

Li, Jun ;

Pan, Jia-Hong ;

Xu, Jeff-Qiang ;

Lin, Jing-Dong ;

Liao, Dai-Wei .

SOLID STATE IONICS, 2007, 178 (13-14) :987-993

← 1 2 3 4 5 →