Equilibrium textures in main-chain liquid crystalline polymers

被引:32
作者
Elias, F [1 ]
Clarke, SM [1 ]
Peck, R [1 ]
Terentjev, EM [1 ]
机构
[1] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
来源
EUROPHYSICS LETTERS | 1999年 / 47卷 / 04期
关键词
D O I
10.1209/epl/i1999-00407-y
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We analyse the Schlieren textures formed by the nematic director in a thermotropic main-chain liquid crystalline polymer. After an initial coarsening, the textures reach a stable time-independent state which appears to bf an equilibrium function of temperature and material parameters, with a characteristic length scale xi of order 2 mu m. In particular, we study the evolution of this domain size when the temperature approaches the nematic-isotropic transition T-ni. The texture size xi increases towards T-ni, but decreases reversibly when the temperature decreases back into the nematic phase. We discuss possible theoretical models that may explain such an equilibrium polydomain state of nematic director and the dependence of its size on the nematic order parameter.
引用
收藏
页码:442 / 448
页数:7
相关论文
共 22 条
[1]   Effect of flexible spacer length on the phase transitions and mesophase structures of main-chain thermotropic liquid-crystalline polyesters having bulky pendent side groups [J].
Chang, S ;
Han, CD .
MACROMOLECULES, 1997, 30 (06) :1670-1684
[2]   LATE-TIME COARSENING DYNAMICS IN A NEMATIC LIQUID-CRYSTAL [J].
CHUANG, I ;
TUROK, N ;
YURKE, B .
PHYSICAL REVIEW LETTERS, 1991, 66 (19) :2472-2479
[3]   COSMOLOGY IN THE LABORATORY - DEFECT DYNAMICS IN LIQUID-CRYSTALS [J].
CHUANG, I ;
DURRER, R ;
TUROK, N ;
YURKE, B .
SCIENCE, 1991, 251 (4999) :1336-1342
[4]   Light-scattering study of random disorder in liquid crystalline elastomers [J].
Clarke, SM ;
Nishikawa, E ;
Finkelmann, H ;
Terentjev, EM .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1997, 198 (11) :3485-3498
[5]   Texture evolution during the polydomain-monodomain transition in nematic elastomers [J].
Clarke, SM ;
Terentjev, EM ;
Kundler, I ;
Finkelmann, H .
MACROMOLECULES, 1998, 31 (15) :4862-4872
[6]  
DEGENNES PG, 1982, POLYM LIQUID CRYSTAL, pCH5
[7]  
Doi M., 1986, The theory of polymer dynamics
[8]   Order-disorder transition in an external field in random ferromagnets and nematic elastomers [J].
Fridrikh, SV ;
Terentjev, EM .
PHYSICAL REVIEW LETTERS, 1997, 79 (23) :4661-4664
[9]  
GOTZ S, 1993, MACROMOLECULES, V26, P1520
[10]  
Haller I., 1975, Progress in Solid State Chemistry, V10, P103, DOI 10.1016/0079-6786(75)90008-4