From engineering crystals to engineering molecules: emergent consequences of controlling reactivity in the solid state using linear templates

被引:13
作者
McGillivray, LR [1 ]
机构
[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA
来源
CRYSTENGCOMM | 2002年 / 4卷 / 07期
关键词
D O I
10.1039/b200332e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Molecules that function as linear templates provide a means to organize two molecules, using the principles of molecular recognition and self-assembly, for a bimolecular reaction. The design and application of linear templates in order to direct reactivity in organic solids, particularly [2 + 2] photoreactivity, is outlined. The linear templates provide control of solid-state reactivity such that it is possible, in a similar way to the liquid phase, to conduct molecular synthesis by design.
引用
收藏
页码:1 / 10
页数:10
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