Plasma Induced Grafting Carboxymethyl Cellulose on Multiwalled Carbon Nanotubes for the Removal of UO22+ from Aqueous Solution

被引:351
作者
Shao, Dadong [1 ]
Jiang, Zhongqing [1 ]
Wang, Xiangke [1 ]
Li, Jiaxing [1 ]
Meng, Yuedong [1 ]
机构
[1] Chinese Acad Sci, Inst Plasma Phys, Key Lab Novel Thin Film Solar Cells, Hefei 230031, Peoples R China
基金
中国国家自然科学基金;
关键词
SINGLE-WALL CARBON; RADICAL POLYMERIZATION; RENEWABLE RESOURCES; FUNCTIONALIZATION; SURFACE; COMPOSITES; ADSORPTION; BEHAVIOR; ACTIVATION; COPOLYMERS;
D O I
10.1021/jp8091094
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carboxymethyl cellulose (CMC) is grafted on multiwalled carbon nanotubes (MWCNT) by using plasma techniques. The CMC grafted MWCNT (MWCNT-g-CMC) is characterized by using Fourier transform infrared spectra (FT-IR), Raman spectra, powder X-ray diffraction (XRD), thermogravimetric analysis (TGA)-differential thermal analysis (DTA), scanning electron microscopy (SEM), and N-2-BET methods in detail. The application of MWCNT-g-CMC in the removal Of UO22+ from aqueous solution is investigated. MWCNT-g-CMC has much higher sorption ability in the removal Of UO22+ than raw MWCNT. The MWCNT-g-CMC is a suitable material in the preconcentration and solidification of heavy metal ions from large volume of aqueous solutions.
引用
收藏
页码:860 / 864
页数:5
相关论文
共 51 条
[1]   FT-Raman spectroscopy of wood: Identifying contributions of lignin and carbohydrate polymers in the spectrum of black spruce (Picea mariana) [J].
Agarwal, UP ;
Ralph, SA .
APPLIED SPECTROSCOPY, 1997, 51 (11) :1648-1655
[2]   A new class of thin film hydrogels produced by plasma polymerization [J].
Bhattacharyya, Dhiman ;
Pillai, Karthikeyan ;
Chyan, Oliver M. R. ;
Tang, Liping ;
Timmons, Richard B. .
CHEMISTRY OF MATERIALS, 2007, 19 (09) :2222-2228
[3]   Characterisation of carboxymethyl cellulose and polyacrylamide graft copolymer [J].
Biswal, DR ;
Singh, RP .
CARBOHYDRATE POLYMERS, 2004, 57 (04) :379-387
[4]   Microwave-induced multiple functionalization of carbon nanotubes [J].
Brunetti, Fulvio G. ;
Herrero, M. Antonia ;
Munoz, Juan de M. ;
Diaz-Ortiz, Angel ;
Alfonsi, Jessica ;
Meneghetti, Moreno ;
Prato, Maurizio ;
Vazquez, Ester .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (25) :8094-8100
[5]   CVD synthesis of carbon nanotubes using a finely dispersed cobalt catalyst and their use in double layer electrochemical capacitors [J].
Chatterjee, AK ;
Sharon, M ;
Baneriee, R ;
Neumann-Spallart, M .
ELECTROCHIMICA ACTA, 2003, 48 (23) :3439-3446
[6]   Polymers from renewable resources: kinetics of 4-vinyl pyridine radiochemical grafting onto cellulose extracted from pine needles [J].
Chauhan, GS ;
Dhiman, SK ;
Guleria, LK ;
Misra, BN ;
Kaur, I .
RADIATION PHYSICS AND CHEMISTRY, 2000, 58 (02) :181-190
[7]   Plasma patterning of carbon nanotubes [J].
Chen, QD ;
Dai, LM .
APPLIED PHYSICS LETTERS, 2000, 76 (19) :2719-2721
[8]   Plasma activation of carbon nanotubes for chemical modification [J].
Chen, QD ;
Dai, LM ;
Gao, M ;
Huang, SM ;
Mau, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (03) :618-622
[9]   Adsorption of polar and nonpolar organic chemicals to carbon nanotubes [J].
Chen, Wei ;
Duan, Lin ;
Zhu, Dongqiang .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (24) :8295-8300
[10]   Ammonia RF-plasma on PTFE surfaces: Chemical characterization of the species created on the surface by vapor-phase chemical derivatization [J].
Chevallier, P ;
Castonguay, N ;
Turgeon, S ;
Dubrulle, N ;
Mantovani, D ;
McBreen, PH ;
Wittmann, JC ;
Laroche, G .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (50) :12490-12497