Tuning the LCST of poly(2-oxazoline)s by varying composition and molecular weight: alternatives to poly(N-isopropylacrylamide)?

被引:373
作者
Hoogenboom, Richard [1 ,2 ]
Thijs, Hanneke M. L. [1 ,2 ]
Jochems, Mark J. H. C. [1 ]
van Lankvelt, Bart M. [1 ]
Fijten, Martin W. M. [1 ,2 ]
Schubert, Ulrich S. [1 ,2 ,3 ]
机构
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands
[3] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany
关键词
D O I
10.1039/b813140f
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
The cloud point of copolymers of 2-ethyl-2-oxazoline and 2-n-propyl-2-oxazoline could be tuned from 25 degrees C to 100 degrees C by varying molecular weight and composition; the reversibility and concentration dependence of the cloud points were evaluated to assess the potential of these copoly(2-oxazoline)s as alternatives to poly(N-isopropylacrylamide).
引用
收藏
页码:5758 / 5760
页数:3
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