Ambient pressure synthesis of corundum-type In2O3

被引：112

作者：

Epifani, M

Siciliano, P

Gurlo, A

Barsan, N

Weimar, U

机构：

[1] CNR, IMM, Sez Lecce, I-73100 Lecce, Italy

[2] Univ Tubingen, Inst Phys & Theoret Chem, D-72076 Tubingen, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 13期

关键词：

D O I：

10.1021/ja0318075

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication reports the formation of the high-pressure modification of indium (III) oxide (so-called corundum-type or hexagonal In2O3) under ambient pressure. Corundum-type In2O3 was obtained by precipitation from the solution of indium nitrate in methanol by adding concentrated ammonia solution and subsequent calcination of the obtained precipitate at 250?500 °C. The role of the impurities and the additives in the stabilization of corundum-type In2O3 is discussed. Copyright © 2004 American Chemical Society.

引用

页码：4078 / 4079

页数：2

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