Relative permittivities, densities, and refractive indices of the binary mixtures of sulfolane with ethylene glycol, diethylene glycol, and poly(ethylene glycol) at 303.15 K

被引:65
作者
Awwad, AM
Al-Dujaili, AH
Salman, HE
机构
[1] Ibn Al Haitham Univ Baghdad, Dept Chem, Coll Educ, Baghdad, Iraq
[2] Appl Res Ctr, Baghdad, Iraq
关键词
D O I
10.1021/je010259c
中图分类号
O414.1 [热力学];
学科分类号
摘要
Relative permittivities (epsilon), densities (rho), and refractive indices (n(D)) were measured for binary mixtures of sulfolane with ethylene glycol, diethylene glycol, poly(ethylene glycol) with an average molecular weight of 200, and poly(ethylene glycol) with an average molecular weight of 600 at 303.15 K over the whole mole fraction range. From these experimental data, the excess molar volumes (V-E), and deviations in refractive indices (Deltan(D)), relative permittivities (Deltaepsilon), and molar polarization (DeltaP(m)) were calculated. These quantities were fitted to the Redlich-Kister polynomial equation to derive the binary adjustable parameters and standard errors.
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页码:421 / 424
页数:4
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