Measuring methods of infinite dilution activity coefficients and a database for systems including water

被引:148
作者
Kojima, K [1 ]
Zhang, SJ [1 ]
Hiaki, T [1 ]
机构
[1] NIHON UNIV, COLL IND TECHNOL, DEPT IND CHEM, NARASHINO, CHIBA 275, JAPAN
关键词
review; activity coefficients; dilute solution; experimental method; database; systems including water;
D O I
10.1016/S0378-3812(96)03210-4
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental techniques for the determination of infinite dilution activity coefficients and their improvements are reviewed, Generally, the measuring techniques can be classified as the indirect and direct methods. The indirect methods include the extrapolations from vapor-liquid equilibrium data and calculations from the other thermodynamic data, such as liquid-liquid equilibrium data, gas-liquid partition coefficient data and so on. The direct methods include the gas-liquid chromatography (GLC) method, headspace GLC method, gas-stripping method, liquid-liquid chromatography method, differential ebulliometry method and differential static method, Also, the most extensively used gas-liquid chromatographic method can be divided into the stationary phase GLC, non-steady-state GLC and relative measurement GLC, A database of infinite dilution activity coefficients, which had been measured and reported by 96 literature sources of journals in the period from 1927 through 1995 for organic compounds in water and water in organic solvents, has also been presented. The database contains a total of 1469 pieces of data of infinite dilution activity coefficients ranging from 283.15 to 373.15 K. No database of infinite dilution activity coefficients for systems including water has been previously reported. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:145 / 179
页数:35
相关论文
共 190 条
[1]   LIMITING ACTIVITY-COEFFICIENTS OF TRIETHYLAMINE IN 30 SOLVENTS BY A SIMPLE GAS-LIQUID-CHROMATOGRAPHIC METHOD [J].
ABRAHAM, MH ;
GRELLIER, PL ;
MANA, J .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1974, 6 (12) :1175-1179
[2]   THERMODYNAMICS OF SOLUTE TRANSFER FROM WATER TO HEXADECANE [J].
ABRAHAM, MH ;
WHITING, GS ;
FUCHS, R ;
CHAMBERS, EJ .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (02) :291-300
[3]  
AIM K, 1988, THERMODYNAMICS FLUID, P105
[4]   APIEZON-L AS A STATIONARY PHASE FOR DETERMINATION OF ACTIVITY-COEFFICIENTS BY LIQUID-LIQUID CHROMATOGRAPHY [J].
ALESSI, P ;
KIKIC, I .
JOURNAL OF CHROMATOGRAPHY, 1974, 97 (01) :15-18
[5]   SIGNIFICANCE OF DILUTE REGIONS [J].
ALESSI, P ;
FERMEGLIA, M ;
KIKIC, I .
FLUID PHASE EQUILIBRIA, 1991, 70 (2-3) :239-250
[6]   LIMITATIONS OF DIFFERENTIAL STATIC APPARATUS IN DILUTE REGIONS [J].
ALESSI, P ;
FERMEGLIA, M ;
KIKIC, I .
FLUID PHASE EQUILIBRIA, 1988, 43 (2-3) :355-358
[7]  
ALESSI P, 1974, GAZZ CHIM ITAL, V104, P739
[8]  
ALESSI P, 1988, THERMODYNAMICS FLUID, P169
[9]  
ALESSI P, 1986, FLUID PHASE EQUILIBR, V29, P249
[10]  
ALESSI P, 1986, COMMUNICATION