Synthesis, electronic and crystal structure of a new organic semiconductor tetramethyltetrathiafulvalene-trinitroresorcinol (2:1), (TMTTF)2(C6H2N3O8)

被引：2

作者：

Abashev, GG

Gritsenko, VV

Kazheva, ON

Tenishev, AG

Canadell, E

Dyachenko, OA ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Russia

[2] Perm State Univ, Inst Nat Sci, Perm 614600, Russia

[3] CSIC, Inst Ciencia Mat Barcelona, E-08193 Bellaterra, Spain

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 2001年 / 216卷 / 12期

关键词：

D O I：

10.1524/zkri.216.12.623.22486

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A new organic semiconductor with trinitroresorcinol as the anion, (TMTTF)(2)(C6HN3O8) (1) (TMTTF: tetramethyltetrathiafulvalene), [GRAPHICS] has been synthesized and its crystal structure has been investigated at room and low temperatures (295 and 110 K). The crystal structure of 1 is formed by one-dimensional stacks of cation-radicals (TMTTF)(+1/2) separated by trinitroresorcinol anions (C6H2N3O8)(-). This novel salt reveals semiconducting properties. Tight-binding band structure calculations for 1 have been carried out in order to understand the charge distribution among the different donors.

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页码：623 / 628

页数：6

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