Quasi-reversible voltammetric response of electrodes coated with electroactive monolayer films

被引：24

作者：

Ohtani, M ^{[1
]}

机构：

[1] Kanazawa Coll Art, Kanazawa, Ishikawa 9208656, Japan

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 1999年 / 1卷 / 10期

关键词：

adsorption; double-layer effect; quasi-reversible electron transfer; voltammetry; simulation;

D O I：

10.1016/S1388-2481(99)00103-4

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Quasi-reversible voltammetric response of the surface-confined redox species is heated, including both ion pairing: and double-layer effects. The Smith-White model and the Butler-Volmer formulation are chosen as the electrode\solution interface model and the electrode kinetics, respectively. An algorithm to simulate the voltammogram is derived. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：488 / 492

页数：5

共 14 条

[1] DISCRETENESS-OF-CHARGE EFFECTS AT MOLECULAR FILMS CONTAINING ACID/BASE GROUPS [J].