NMR studies on the diffusion of hydrocarbons on the metal-organic framework material MOF-5

被引：194

作者：

Stallmach, F

Gröger, S

Künzel, V

Kärger, J

Yaghi, OM

Hesse, M

Müller, U

机构：

[1] Univ Leipzig, Fak Phys & Geowissensch, D-04103 Leipzig, Germany

[2] BASF AG, D-67056 Ludwigshafen, Germany

[3] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期

关键词：

alkanes; benzene; diffusion; microporous materials; NMR spectroscopy;

D O I：

10.1002/anie.200502553

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On the move: High intracrystalline mobilities and fast exchange between the crystal and the surrounding gas phase were found in NMR studies on the diffusion of methane, ethane, n-hexane, and benzene in large crystals of the metal-organic framework MOF-5 (see SEM image). The results support future use of metal-organic framework materials as tailorable sorbents for fast gas processing and gas-storage materials in industry. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2123 / 2126

页数：4

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