Nonflammable electrolyte for safer non-aqueous sodium batteries

被引：75

作者：

Feng, Jinkui ^{[1
]}

An, Yongling ^{[1
]}

Ci, Lijie ^{[1
]}

Xiong, Shenglin ^{[2
]}

机构：

[1] Shandong Univ, Sch Mat Sci & Engn, Key Lab Liquid Solid Struct Evolut & Proc Mat, Minist Educ, Jinan 250061, Peoples R China

[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 28期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

LITHIUM-ION BATTERIES; NON-FLAMMABLE ELECTROLYTE; INSERTION; SOLVENT; REACTIVITY; MECHANISMS; NANOWIRES; PHOSPHATE; STORAGE; ETHER;

D O I：

10.1039/c5ta03548a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sodium batteries are now considered as promising low-cost alternatives for lithium batteries. However, safety problems such as fire and explosion during abuse-testing conditions hinder the development of room temperature sodium batteries. To address these issues, here we propose a nonflammable electrolyte system for sodium batteries. By introducing a high-efficiency flame-retarding additive, the carbonate based electrolyte becomes flame inhibiting. Moreover, the additive can improve the cyclability of both the acetylene black (AB) anode and the Na0.44MnO2 cathode.

引用

页码：14539 / 14544

页数：6

共 23 条

[1] A novel non-flammable electrolyte containing methyl nonafluorobutyl ether for lithium secondary batteries [J].

Arai, J .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2002, 32 (10) :1071-1079

[2] Safety mechanisms in lithium-ion batteries [J].

Balakrishnan, PG ;

Ramesh, R ;

Kumar, TP .

JOURNAL OF POWER SOURCES, 2006, 155 (02) :401-414

[3] Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications [J].

Cao, Yuliang ;

Xiao, Lifen ;

Sushko, Maria L. ;

Wang, Wei ;

Schwenzer, Birgit ;

Xiao, Jie ;

Nie, Zimin ;

Saraf, Laxmikant V. ;

Yang, Zhengguo ;

Liu, Jun .

NANO LETTERS, 2012, 12 (07) :3783-3787

[4] Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life [J].

Cao, Yuliang ;

Xiao, Lifen ;

Wang, Wei ;

Choi, Daiwon ;

Nie, Zimin ;

Yu, Jianguo ;

Saraf, Laxmikant V. ;

Yang, Zhenguo ;

Liu, Jun .

ADVANCED MATERIALS, 2011, 23 (28) :3155-+

[5] Dimethyl methyl phosphate: A new nonflammable electrolyte solvent for lithium-ion batteries [J].

Feng, J. K. ;

Sun, X. J. ;

Ai, X. P. ;

Cao, Y. L. ;

Yang, H. X. .

JOURNAL OF POWER SOURCES, 2008, 184 (02) :570-573

[6] Ether-based nonflammable electrolyte for room temperature sodium battery [J].

Feng, Jinkui ;

Zhang, Zhen ;

Li, Lifei ;

Yang, Jian ;

Xiong, Shenglin ;

Qian, Yitai .

JOURNAL OF POWER SOURCES, 2015, 284 :222-226

[7] Unsaturated phosphazenes as co-solvents for lithium-ion battery electrolytes [J].

Harrup, Mason K. ;

Rollins, Harry W. ;

Jamison, David K. ;

Dufek, Eric J. ;

Gering, Kevin L. ;

Luther, Thomas A. .

JOURNAL OF POWER SOURCES, 2015, 278 :794-801

[8] Controlling SEI Formation on SnSb-Porous Carbon Nanofibers for Improved Na Ion Storage [J].

Ji, Liwen ;

Gu, Meng ;

Shao, Yuyan ;

Li, Xiaolin ;

Engelhard, Mark H. ;

Arey, Bruce W. ;

Wang, Wei ;

Nie, Zimin ;

Xiao, Jie ;

Wang, Chongmin ;

Zhang, Ji-Guang ;

Liu, Jun .

ADVANCED MATERIALS, 2014, 26 (18) :2901-2908

[9] Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries [J].

Komaba, Shinichi ;

Murata, Wataru ;

Ishikawa, Toru ;

Yabuuchi, Naoaki ;

Ozeki, Tomoaki ;

Nakayama, Tetsuri ;

Ogata, Atsushi ;

Gotoh, Kazuma ;

Fujiwara, Kazuya .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (20) :3859-3867

[10] The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage [J].

Kundu, Dipan ;

Talaie, Elahe ;

Duffort, Victor ;

Nazar, Linda F. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (11) :3431-3448

← 1 2 3 →