Orientational elastic constants of polymer comblike nematic

被引:5
作者
Filippov, AP [1 ]
Andreeva, LN [1 ]
Barmatov, EB [1 ]
Shibaev, VP [1 ]
机构
[1] MOSCOW MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 119899,RUSSIA
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1997年 / 299卷
关键词
D O I
10.1080/10587259708041986
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Elastic deformations of uniformly orientated layers of thermotropic polymeric comblike nematic in magnetic field were studied using the method of Freedericksz transitions. The temperature dependences of splay K-1 and bend K-3 elastic constants and optical anisotropy were determined. On clanging of the relative temperature Delta T = T - T-o from -0.5 to -60 degrees C, the optical anisotropy increases from 0.05 to 0.1. This experimental fact shows double increase of order parameter. It was found that in investigated temperature range the splay constant values are slightly more then the bend constant values (K-1/K-3 similar to 0.8).
引用
收藏
页码:143 / 148
页数:6
相关论文
共 15 条
[1]  
BLINOV LM, 1978, ELEKTRO MAGNITOOPTIK
[2]   VISCOELASTIC PROPERTIES OF SIDE-CHAIN MESOMORPHIC POLYMERS IN NEMATIC PHASE - MELT AND SOLUTIONS [J].
CASAGRANDE, C ;
FABRE, P ;
VEYSSIE, M ;
WEILL, C ;
FINKELMANN, H .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1984, 113 (1-4) :193-200
[3]  
DEJEU WH, 1980, PHYSICAL PROPERTIES
[4]  
Fréedericksz V, 1931, Z KRISTALLOGR, V79, P255
[5]  
FREEDERICKZS V, 1934, PHYS Z SOWJETUNION, V6, P490
[6]  
FREYDZON YS, 1987, VYSOKOMOL SOEDIN A, V27, P1464
[8]   MEASUREMENT OF THE ORIENTATIONAL ELASTIC-CONSTANTS AND THE TWIST VISCOSITY OF NEMATIC SIDE-CHAIN POLYMERS [J].
RUPP, W ;
GROSSMANN, HP ;
STOLL, B .
LIQUID CRYSTALS, 1988, 3 (05) :583-592
[9]   DIE BIEGUNGSELASTIZITAT DER NEMATISCHEN PHASE VON AZOXYANISOL [J].
SAUPE, A .
ZEITSCHRIFT FUR NATURFORSCHUNG PART A-ASTROPHYSIK PHYSIK UND PHYSIKALISCHE CHEMIE, 1960, 15 (09) :815-822
[10]  
Tsvetkov V., 1942, ACTA PHYSICOCHIM, V16, P132