Palladium N-methylimidazolium supported complexes as efficient catalysts for the Heck reaction

被引:71
作者
Altava, B [1 ]
Burguete, MI [1 ]
García-Verdugo, E [1 ]
Karbass, N [1 ]
Luis, SV [1 ]
Puzary, A [1 ]
Sans, V [1 ]
机构
[1] Univ Jaume 1, CSIC, Dept Quim Inorgan & Organ, E-12071 Castellon de La Plana, Spain
关键词
supported catalysts; polymer; Heck reaction; facilitated chemical synthesis;
D O I
10.1016/j.tetlet.2006.02.023
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Different N-methylimidazolium supported ligands have been easily synthesized. The palladium complexes derived from those materials can be used for the catalysis of the Heck reaction giving excellent yields, selectivities and very good TON and TOF values. The Supported Pd-pincer complexes show an increased stability, and provide a clear improvement in the recovery and reuse for the Supported catalysts. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2311 / 2314
页数:4
相关论文
共 34 条
  • [1] Non-conventional methodologies for transition-metal catalysed carbon-carbon coupling: a critical overview. Part 1: The Heck reaction
    Alonso, F
    Beletskaya, IP
    Yus, M
    [J]. TETRAHEDRON, 2005, 61 (50) : 11771 - 11835
  • [2] The use of NIR-FT-Raman spectroscopy for the characterization of polymer-supported reagents and catalysts
    Altava, B
    Burguete, MI
    García-Verdugo, E
    Luis, SV
    Vicent, MJ
    [J]. TETRAHEDRON, 2001, 57 (41) : 8675 - 8683
  • [3] Preparation of polymer-supported palladium/N-heterocyclic carbene complex for Suzuki cross-coupling reactions
    Byun, JW
    Lee, YS
    [J]. TETRAHEDRON LETTERS, 2004, 45 (09) : 1837 - 1840
  • [4] Palladium catalysis in synthesis: where next?
    Fairlamb, IJS
    [J]. TETRAHEDRON, 2005, 61 (41) : 9661 - 9662
  • [5] A sensitive colorimetric method for the study of polystyrene Merrifield resins and chloromethylated macroporous monolithic polymers
    Galindo, F
    Altava, B
    Burguete, MI
    Gavara, R
    Luis, SV
    [J]. JOURNAL OF COMBINATORIAL CHEMISTRY, 2004, 6 (06): : 859 - 861
  • [6] Introduction: Recoverable catalysts and reagents - Perspective and prospective
    Gladysz, JA
    [J]. CHEMICAL REVIEWS, 2002, 102 (10) : 3215 - 3216
  • [7] Pd-PVP colloid as catalyst for Heck and carbonylation reactions:: TEM and XPS studies
    Gniewek, A
    Trzeciak, AM
    Ziólkowski, JJ
    Kepinski, L
    Wrzyszcz, J
    Tylus, W
    [J]. JOURNAL OF CATALYSIS, 2005, 229 (02) : 332 - 343
  • [8] Herrmann WA, 2002, ANGEW CHEM INT EDIT, V41, P1290, DOI 10.1002/1521-3773(20020415)41:8<1290::AID-ANIE1290>3.0.CO
  • [9] 2-Y
  • [10] Phospha-palladacycles and N-heterocyclic carbene palladium complexes:: efficient catalysts for CC-coupling reactions
    Herrmann, WA
    Öfele, K
    Von Preysing, D
    Schneider, SK
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 687 (02) : 229 - 248